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Chloro(1.5-cyclooctadiene)iridium(I) dimer|12112-67-3

Release time:2021-02-23 14:51viewed:times
 

Description

Cyclooctadiene iridium chloride dimer is an organoiridium compound with the formula Ir2Cl2(C8H12)2, where C8H12 is the diene 1,5-cyclooctadiene. It is an orange solid that is soluble in organic solvents. The complex is used as a precursor to other iridium complexes, some of which are used in homogeneous catalysis. The solid is air-stable but its solutions degrades in air.

Basic Info

Chemical Name Chloro(1,5-cyclooctadiene)iridium(I) dimer
Synonyms

(1Z,5Z)-cycloocta-1,5-diene,iridium,dichloride;Chloro-1,5-cyclooctadiene-iridium(I) dimer;Bis(1,5-cyclooctadiene)diiridium(I) Dichloride;

CAS No. 12112-67-3
Molecular Formula C16H24Cl2Ir2
Molecular Weight 671.70200
PSA 0.00000
LogP 6.72460

Numbering system

PubChem number 24856629
EINECS number 235-170-7
MDL number MFCD00012414

Properties

Appearance & Physical State red-orange powder.
Boiling Point 153.5ºC at 760 mmHg
Melting Point 205ºC (dec.)
Flash Point 31.7ºC
Storage Condition 2-8ºC
Vapor Pressure 4.25mmHg at 25°C

Safety Info

Safety Statements S26; S37/39
WGK Germany 3
Risk Statements R36/37/38
Hazard Codes Xi
Hazard Declaration H315; H319; H335
Symbol GHS07
Caution Statement P261; P305 + P351 + P338
Signal Word Warning

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